羧乙基壳聚糖蒙脱石吸附养殖水体中Cu²⁺的应用     

李俭平  周忻宇  代婧炜  沈庆洲 《海洋科学》2020,44(2):120-130

为了寻求性能良好、环保吸附剂,用于去除养殖水体中重金属Cu~(2+),作者利用蒙脱石负载羧乙基壳聚糖制备成复合吸附剂,并利用IR、SEM、XRD等手段分析其表面性能,将其用于处理Cu~(2+)溶液,考察了环境因子对其吸附性能的影响,并从吸附动力学和吸附热力学角度分析吸附剂对Cu~(2+)的吸附机理,最后考察其再生利用效果。结果表明:羧乙基壳聚糖成功进入到蒙脱石层间;在羧乙基壳聚糖与蒙脱石质量比为1︰25、40℃恒温水浴搅拌60min、pH=6.0、最佳投加量为4.0g/L、处理浓度不超过30 mg/L Cu~(2+)溶液时,复合吸附剂对Cu~(2+)去除率可以达到96.23%,将其用于淡水养殖鱼塘水体中, Cu~(2+)去除后可达到《渔业水质标准》规定;吸附剂对Cu~(2+)吸附热力学实验结果表明,符合Langmuir模型,反应过程为自发、吸热反应;吸附动力学结果表明该吸附符合准二级动力学方程,反应属于化学吸附;再生实验中NaOH的再生效果优于HCl。  相似文献   

基于核函数NPSSB模型的HY-2A卫星雷达高度计海况偏差研究     

张洁  田杰  王兆徽 《海洋预报》2020,37(1):1-10

利用机器学习的方法,对14个周期HY-2A卫星高度计数据:风速、有效波高和海面高度差值进行训练,探究海况偏差和风速、有效波高之间的关系,创建海况偏差核函数非参数模型(NPSSB),并与参数模型中具有代表性的BM3、BM4模型进行对比。研究表明:(1)核函数NPSSB模型能够很好的反映SSB与U、SWH之间的关系,SSB与U呈二次函数关系,SSB与SWH呈反比例函数关系;(2)核函数NPSSB模型对SSB的模拟能力与训练数据集相关,数据量越多,模拟能力越好;(3)核函数NPSSB模型与BM3、BM4模型都存在0^-0.03 m的差值,随着风速和有效波高的增加,差值的绝对值越大。  相似文献   

HY-2B卫星散射计海面风场产品质量分析 *     

陈克海  解学通  张金兰  邹巨洪  张毅 《热带海洋学报》2020,39(6):30-40

星载微波散射计是获取全球海面风场信息的主要手段, HY-2B卫星散射计的成功发射为全球海面风场数据获取的持续性提供了重要保障。本文利用欧洲中期天气预报中心(European Center for Medium-Range Weather Forecasts, ECMWF)再分析风场数据、热带大气海洋观测计划(Tropical Atmosphere Ocean Array, TAO)和美国国家数据浮标中心(National Data Buoy Center, NDBC)浮标获取的海面风矢量实测数据, 对HY-2B散射计海面风场数据产品的质量进行统计分析。分析表明, HY-2B风场与ECMWF再分析风场对比, 在4~24m·s^-1风速区间内, 风速和风向均方根误差(root mean square error, RMSE)分别为1.58m·s^-1和15.34°; 与位于开阔海域的TAO浮标数据对比, 风速、风向RMSE分别为1.03m·s^-1和14.98°, 可见HY-2B风场能较好地满足业务化应用的精度要求(风速优于2m·s^-1, 风向优于20°)。与主要位于近海海域的NDBC浮标对比, HY-2B风场的风速、风向RMSE分别为1.60m·s^-1和19.14°, 说明HY-2B散射计同时具备了对近海海域风场的良好观测能力。本文还发现HY-2B风场质量会随风速、地面交轨位置等变化, 为用户更好地使用HY-2B风场产品提供参考。  相似文献   

Cu2+对序批式反应器中活性污泥胞外聚合物产量及其组分的影响     

李姗姗  朱四富  马丙瑞  于娜玲  赵长坤  信帅帅  潘云浩  吴淑妍  武原原  高孟春 《中国海洋大学学报(自然科学版)》2020,(2):107-115

研究了长期暴露条件下Cu2+对序批式反应器(SBR)性能及其活性污泥胞外聚合物(EPS)特性的影响。结果表明,进水中加入10 mg·L-1的Cu2+后,在SBR运行的第16~55天,COD和NH+4-N的去除率保持稳定;在第56~75天,COD和NH+4-N的平均去除率与进水Cu2+浓度为0 mg·L-1时相比分别下降了3.88%和6.41%。浓度为10 mg·L-1的Cu2+长期作用下,活性污泥中EPS、松散附着EPS(LB-EPS)和紧密附着EPS(TB-EPS)产量及LB-EPS和TB-EPS中蛋白质(PN)含量增加。傅里叶变换红外光谱分析表明10 mg·L-1 Cu2+的长期暴露导致TB-EPS中PN的C=O键、N-H键和C-O键相对含量降低。X射线光电子能谱(XPS)测试结果显示在10 mg·L-1 Cu2+长期暴露条件下,LB-EPS和TB-EPS中元素Cu和O百分含量增加。  相似文献   

A Review of the Calculation Formula for the Four-component Borehole Strainmeter and Application to Earthquake Cases   总被引：1，自引：0，他引：1  

SU Kaizhi 《中国地震研究》2019,33(1):132-146

Based on the principle formula for the four-component strainmeters, we can directly obtain the specific plane strain, shear strain and azimuthal angle of the principal strain, and the maximum and minimum principal strains calculated afterwards are the indirect result. The problems of practicality of the sensitivity coefficients A and B of plane strain and shear strain are then discussed. Based on this idea, we analyzed the observation data of several four-component borehole strainmeters near the epicenter of the Yiliang M_S5.7 earthquake in 2012 and the Ludian M_S6.5 earthquake in 2014 in the Zhaotong area, Yunnan Province. The results show that the analysis based on the perspective of plane strain and shear strain has an obviously better effect than that based on the component readings, and can directly peel off the respective abnormality of the plane strain and shear strain. In addition, the correlation coefficient curves between measured data of two plane strains show significant anomalies which often occur several days before and during the earthquake.  相似文献   

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data     

Maofei Jiang  Ke Xu  Yalong Liu 《Marine Geodesy》2018,41(3):289-312

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.  相似文献   

Inference of in situ stress from thermoporoelastic borehole breakouts based on artificial neural network     

Hua Zhang  Shunde Yin 《国际地质力学数值与分析法杂志》2019,43(16):2493-2511

The determination of in situ stresses is very important in petroleum engineering. Hydraulic fracturing is a widely accepted technique for the determination of in situ stresses nowadays. Unfortunately, the hydraulic fracturing test is time-consuming and expensive. Taking advantage of the shape of borehole breakouts measured from widely available caliper and image logs to determine in situ stress in petroleum engineering is highly attractive. By finite element modeling of borehole breakouts considering thermoporoelasticity, the authors simulate the process of borehole breakouts in terms of initiation, development, and stabilization under Mogi-Coulomb criterion and end up with the shape of borehole breakouts. Artificial neural network provides such a tool to establish the relationship between in situ stress and shape of borehole breakouts, which can be used to determine in situ stress based on different shape of borehole breakouts by inverse analysis. In this paper, two steps are taken to determine in situ stress by inverse analysis. First, sets of finite element modeling provide sets of data on in situ stress and borehole breakout measures considering the influence of drilling fluid temperature and pore pressure, which will be used to train an artificial neural network that can eventually represent the relationship between the in situ stress and borehole breakout measures. Second, for a given measure of borehole breakouts in a certain drilling fluid temperature, the trained artificial neural network will be used to predict the corresponding in situ stress. Results of numerical experiments show that the inverse analysis based on finite element modeling of borehole breakouts and artificial neural network is a promising method to determine in situ stress.  相似文献   

随机森林模型在遥感水深反演中的应用     

邱耀炜  沈蔚  纪茜 《海洋技术学报》2019,38(5)

随着我国浅海测绘需求的日益增长,文中利用四波段的WorldView-2高分辨率遥感影像,选取我国南海西沙群岛中的甘泉岛和台湾南湾地区作为典型试验区,开展水深反演研究。引入随机森林算法构建了随机森林水深反演模型,并同常用的3种水深反演模型进行精度对比。结果表明,在甘泉岛和南湾地区随机森林模型反演的水深值和真实水深值的RMSE分别为0.85 m和1.59 m,MRE分别为8%和12%,均优于其他3种模型。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Mapping wetland characteristics using temporally dense Sentinel-1 and Sentinel-2 data: A case study in the St. Lucia wetlands,South Africa     

《International Journal of Applied Earth Observation and Geoinformation》2020

Wetlands have been determined as one of the most valuable ecosystems on Earth and are currently being lost at alarming rates. Large-scale monitoring of wetlands is of high importance, but also challenging. The Sentinel-1 and -2 satellite missions for the first time provide radar and optical data at high spatial and temporal detail, and with this a unique opportunity for more accurate wetland mapping from space arises. Recent studies already used Sentinel-1 and -2 data to map specific wetland types or characteristics, but for comprehensive wetland characterisations the potential of the data has not been researched yet. The aim of our research was to study the use of the high-resolution and temporally dense Sentinel-1 and -2 data for wetland mapping in multiple levels of characterisation. The use of the data was assessed by applying Random Forests for multiple classification levels including general wetland delineation, wetland vegetation types and surface water dynamics. The results for the St. Lucia wetlands in South Africa showed that combining Sentinel-1 and -2 led to significantly higher classification accuracies than for using the systems separately. Accuracies were relatively poor for classifications in high-vegetated wetlands, as subcanopy flooding could not be detected with Sentinel-1’s C-band sensors operating in VV/VH mode. When excluding high-vegetated areas, overall accuracies were reached of 88.5% for general wetland delineation, 90.7% for mapping wetland vegetation types and 87.1% for mapping surface water dynamics. Sentinel-2 was particularly of value for general wetland delineation, while Sentinel-1 showed more value for mapping wetland vegetation types. Overlaid maps of all classification levels obtained overall accuracies of 69.1% and 76.4% for classifying ten and seven wetland classes respectively.  相似文献